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- W1984178855 abstract "The gas phase reactions of O with some first row transition metal complexes have been investigated using Fourier transform ion-cyclotron resonance spectroscopy. O, generated by dissociative electron capture from N2O, reacts with M(CO)x, (M = V, Cr, Fe) and manganese(methylcyclopentadienyl)(CO)3 to generate ML(CO)n−1, exclusively. Thermochemical arguments indicate the products cannot be generated by a simple dissociative electron-transfer mechanism, but must result from loss of CO2. Although the reactions that generate the metal anion complexes and CO2 are > 95 kcal mol−1 exothermic, the metal carbonyl anion products do not subsequently decompose indicating non-statistical energy disposal in the products. The order of relative rate constants for the reactions of the homoleptic carbonyl complexes [kII(O−./V(CO)6) > kII(O−./Cr(CO)6) > kII(O−./Fe(CO)5)] and the product energy disposal results support an addition/elimination mechanism. ca]†|Author to whom correspondence should be addressed." @default.
- W1984178855 created "2016-06-24" @default.
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- W1984178855 date "1991-01-01" @default.
- W1984178855 modified "2023-10-12" @default.
- W1984178855 title "Decarboxylation in the reactions of O. with metal carbonyl complexes in the gas phase" @default.
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- W1984178855 doi "https://doi.org/10.1016/s0277-5387(00)86214-2" @default.
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