Matches in SemOpenAlex for { <https://semopenalex.org/work/W1984192010> ?p ?o ?g. }
- W1984192010 abstract "N,N′-Dicyclohexyldithiooxamide (H2L) reacted with HgX2(X = SCN or Cl) to form the novel mercury mixed-ligand complexes [Hg(H2L)(SCN)2]1, [HgCl2(H2L)]2 and [{HgCl2(H2L)}2]·EtOH 3. The crystal and molecular structures of 1 and 3 have been determined. Crystals of 1 are monoclinic, space group P21/n(no. 14), with a= 11.318(1), b= 17.727(2), c= 11.536(2)A, β= 109.08(2)° and Z= 4. Crystals of 3 are monoclinic, space group P21(no. 4), with a= 8.563(1), b= 21.414(3), c= 11.649(2)A, β= 103.58(2)° and Z= 2. The structures were each refined by a full-matrix least-squares procedure to R1 = 0.031 for 2218 reflections with F2 2.0σ(F2) for 1 and R1 = 0.047 (2374 reflections) for 3. Complex 1 is mononuclear with HgS4 units linked by short intermolecular S ⋯ S interactions. Complex 3 is a binuclear zwitterionic system with one S,S′-chelating H2L ligand bonded to a mercury atom and a second ligand acting in an unusual' conformation as a S,S′-bidentate bridging group between the ionic species HgS2Cl+ and HgCl3–. The two mercury atoms are separated at a non-interacting distance. The infrared spectra of the complexes in the range 650–200 cm–1 are discussed in the light of the known structures." @default.
- W1984192010 created "2016-06-24" @default.
- W1984192010 creator A5004571509 @default.
- W1984192010 creator A5030715383 @default.
- W1984192010 creator A5057336452 @default.
- W1984192010 date "1995-01-01" @default.
- W1984192010 modified "2023-09-24" @default.
- W1984192010 title "Synthesis and solid-state structural characterization of N,N′-dicyclohexyldithiooxamide complexes of HgX2(X = SCN or Cl)" @default.
- W1984192010 cites W1968350029 @default.
- W1984192010 cites W1972194722 @default.
- W1984192010 cites W1972463789 @default.
- W1984192010 cites W1981983254 @default.
- W1984192010 cites W1982142209 @default.
- W1984192010 cites W1983332122 @default.
- W1984192010 cites W1983669351 @default.
- W1984192010 cites W1987698676 @default.
- W1984192010 cites W1991259123 @default.
- W1984192010 cites W1997970678 @default.
- W1984192010 cites W2000440252 @default.
- W1984192010 cites W2000785972 @default.
- W1984192010 cites W2005216254 @default.
- W1984192010 cites W2005574257 @default.
- W1984192010 cites W2009955781 @default.
- W1984192010 cites W2010042208 @default.
- W1984192010 cites W2016567958 @default.
- W1984192010 cites W2018637740 @default.
- W1984192010 cites W2020864304 @default.
- W1984192010 cites W2020954737 @default.
- W1984192010 cites W2026228805 @default.
- W1984192010 cites W2030270322 @default.
- W1984192010 cites W2030841140 @default.
- W1984192010 cites W2032454997 @default.
- W1984192010 cites W2034249506 @default.
- W1984192010 cites W2044292946 @default.
- W1984192010 cites W2053055738 @default.
- W1984192010 cites W2061727803 @default.
- W1984192010 cites W2064482416 @default.
- W1984192010 cites W2068415501 @default.
- W1984192010 cites W2070876656 @default.
- W1984192010 cites W2085007456 @default.
- W1984192010 cites W2087419671 @default.
- W1984192010 cites W2088569652 @default.
- W1984192010 cites W2093736016 @default.
- W1984192010 cites W2951111437 @default.
- W1984192010 doi "https://doi.org/10.1039/dt9950000987" @default.
- W1984192010 hasPublicationYear "1995" @default.
- W1984192010 type Work @default.
- W1984192010 sameAs 1984192010 @default.
- W1984192010 citedByCount "11" @default.
- W1984192010 countsByYear W19841920102013 @default.
- W1984192010 countsByYear W19841920102014 @default.
- W1984192010 countsByYear W19841920102019 @default.
- W1984192010 countsByYear W19841920102020 @default.
- W1984192010 crossrefType "journal-article" @default.
- W1984192010 hasAuthorship W1984192010A5004571509 @default.
- W1984192010 hasAuthorship W1984192010A5030715383 @default.
- W1984192010 hasAuthorship W1984192010A5057336452 @default.
- W1984192010 hasConcept C115624301 @default.
- W1984192010 hasConcept C116569031 @default.
- W1984192010 hasConcept C153642686 @default.
- W1984192010 hasConcept C166950319 @default.
- W1984192010 hasConcept C170493617 @default.
- W1984192010 hasConcept C178516000 @default.
- W1984192010 hasConcept C178790620 @default.
- W1984192010 hasConcept C185592680 @default.
- W1984192010 hasConcept C32909587 @default.
- W1984192010 hasConcept C55493867 @default.
- W1984192010 hasConcept C61276311 @default.
- W1984192010 hasConcept C71240020 @default.
- W1984192010 hasConcept C8010536 @default.
- W1984192010 hasConceptScore W1984192010C115624301 @default.
- W1984192010 hasConceptScore W1984192010C116569031 @default.
- W1984192010 hasConceptScore W1984192010C153642686 @default.
- W1984192010 hasConceptScore W1984192010C166950319 @default.
- W1984192010 hasConceptScore W1984192010C170493617 @default.
- W1984192010 hasConceptScore W1984192010C178516000 @default.
- W1984192010 hasConceptScore W1984192010C178790620 @default.
- W1984192010 hasConceptScore W1984192010C185592680 @default.
- W1984192010 hasConceptScore W1984192010C32909587 @default.
- W1984192010 hasConceptScore W1984192010C55493867 @default.
- W1984192010 hasConceptScore W1984192010C61276311 @default.
- W1984192010 hasConceptScore W1984192010C71240020 @default.
- W1984192010 hasConceptScore W1984192010C8010536 @default.
- W1984192010 hasLocation W19841920101 @default.
- W1984192010 hasOpenAccess W1984192010 @default.
- W1984192010 hasPrimaryLocation W19841920101 @default.
- W1984192010 hasRelatedWork W1965129945 @default.
- W1984192010 hasRelatedWork W1967157923 @default.
- W1984192010 hasRelatedWork W1970417866 @default.
- W1984192010 hasRelatedWork W1971719285 @default.
- W1984192010 hasRelatedWork W1972029387 @default.
- W1984192010 hasRelatedWork W1982142209 @default.
- W1984192010 hasRelatedWork W2009360612 @default.
- W1984192010 hasRelatedWork W2020659167 @default.
- W1984192010 hasRelatedWork W2023892688 @default.
- W1984192010 hasRelatedWork W2075656990 @default.
- W1984192010 hasRelatedWork W2089783706 @default.
- W1984192010 hasRelatedWork W2113429301 @default.
- W1984192010 hasRelatedWork W2144501009 @default.
- W1984192010 hasRelatedWork W2170159573 @default.