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• W1984217619 startingPage "2190" @default.
• W1984217619 abstract "While usual atomic population methods give a consistent view of trivalent lanthanide or a uranium−ligand bond, the description of the bonding of americium(III), which is a key element for nuclear fuel processes, is a challenge. Neither experimental data nor theoretical calculations have been able so far to evidence covalency effects in the americium−ligand bond. We show herein that the use of more sophisticated methods based on a topological approach (AIM and ELF) gives a consistent view of such an interaction for the first time, showing a weak covalent back-bonding interaction with the CO ligand." @default.
• W1984217619 created "2016-06-24" @default.
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• W1984217619 date "2006-01-28" @default.
• W1984217619 modified "2023-09-30" @default.
• W1984217619 title "A Comprehensive Theoretical View of the Bonding in Actinide Molecular Complexes" @default.
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• W1984217619 doi "https://doi.org/10.1021/ja056908c" @default.
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