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- W1984231149 abstract "Potentiometric titrations of solutions of various aromatic hydrocarbons in 1,2-dimethoxyethane and tetrahydrofuran with a solution of biphenylsodium have shown chemical reduction to proceed in two stages: The reduction potentials of the aromatic hydrocarbons, calculated from the potentiometric curve, are in good agreement with the half-wave potentials obtained from polarographic reductions in 96% dioxan-water. The standard potentials of the first reduction step expressed in Volts against the standard potential of biphenyl fit the following equation: with γ = - 2.19 ± 0.059 e.V. (2 × stand. dev. from mean) in which a stands for the root of the m.o. secular equation (overlap S = 0.25 included) corresponding to the lowest non-occupied π-orbital of the hydrocarbon and γ is the resonance-parameter. The electrochemical series of aromatic hydrocarbons including a rough estimate of the standard potential of sodium in 1,2-dimethoxyethane and the mechanism of chemical reduction in inert and proton-active solvents are discussed." @default.
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- W1984231149 date "1956-01-01" @default.
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- W1984231149 title "Reduction potentials of various aromatic hydrocarbons and their univalent anions" @default.
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- W1984231149 doi "https://doi.org/10.1002/recl.19560750502" @default.
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