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- W1984265949 abstract "The kinetics and mechanism of the solid-state reaction in BaTiO3 powder synthesis were investigated microstructurally. An equimolar mixture of BaCO3 and TiO2 (rutile) powders calcinated at 600 and 800 °C in air was observed by using transmission electron microscopy (TEM). During the reaction, layered BaTiO3 was formed over the TiO2 particles with a structurally and compositionally sharp interface. The crystallographic orientation relationship between TiO2 and BaTiO3 was universally observed as [001]TiO2∥[110]BTO, (100)TiO2∥(111)BTO. The perovskite phase BaTiO3 was formed by inward diffusion of barium and oxygen ions into the rutile lattice, maintaining a topotaxial relationship with the rutile structure." @default.
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- W1984265949 date "2008-03-21" @default.
- W1984265949 modified "2023-10-02" @default.
- W1984265949 title "Microstructure Analysis of Solid-State Reaction in Synthesis of BaTiO<sub>3</sub>Powder Using Transmission Electron Microscope" @default.
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- W1984265949 doi "https://doi.org/10.1143/apex.1.041602" @default.
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