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• W1984276985 endingPage "942" @default.
• W1984276985 startingPage "935" @default.
• W1984276985 abstract "Homolytic M−H bond dissociation enthalpies (BDEs) of the mononuclear cationic metal hydride complexes HMLn+, where MLn = Cr(CO)2(dppm)2, Mo(CO)2(L−L)2, W(CO)3(PR3)3, W(CO)2(dppm)2, W(CO)3(tripod), W(CO)3(triphos), Cp*Re(CO)2(PR3), Fe(CO)3(PR3)2, Fe(CO)3(L−L), Cp*2Ru, CpRu(PMe3)2I, CpRu(L−L)H, CpRu(PPh3)2H, Cp*2Os, CpOs(PR3)2Br, CpOs(PPh3)2Cl, CpOs(PPh3)2H, CpIr(CO)(PR3), CpIr(CS)(PPh3), (C5MenH5-n)Ir(COD), Cp*Ir(CO)(PR3), and Cp*Ir(CO)2, have been estimated by use of a thermochemical cycle that requires a knowledge of the heats of protonation (ΔHHM) and redox potentials (E1/2) for the oxidation of the neutral metal complexes (MLn). Excellent correlations were found between −ΔHHM and E1/2 within related series of complexes. The BDE values obtained by this method fall in the range 56−75 kcal/mol. For related complexes of a given metal, the energy required for homolytic M−H bond cleavage (BDE) increases linearly as −ΔHHM for heterolytic M-H bond cleavage increases. For analogous complexes with different metals, the M−H BDE values are greater for third-row than second-row and first-row metals, the difference being 1−12 kcal/mol. Other trends in BDE values are also discussed." @default.
• W1984276985 created "2016-06-24" @default.
• W1984276985 creator A5056246750 @default.
• W1984276985 creator A5067180086 @default.
• W1984276985 date "1996-01-01" @default.
• W1984276985 modified "2023-09-23" @default.
• W1984276985 title "Metal−Hydrogen Bond Dissociation Enthalpies in Series of Complexes of Eight Different Transition Metals" @default.
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• W1984276985 doi "https://doi.org/10.1021/ja9441930" @default.

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