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- W1984287462 abstract "The growth of titanium carbide crystals from the TiCl4-CH4-H2 system was studied using a flow method. The deposition substrates were graphite plates and mullite tubes heated externally. Only polyhedral microcrystallites were formed on graphite plates. On the mullite substrate tubes, polyhedral microcrystallites were deposited at the temperature lower than 1360°C and whiskers with diameters of 10–300 μm grew above 1360°C. Whiskers were obtained at [CH4]/[TiCl4] ⩽ 1 and PTiCl4 = 7.7– 31.0 Torr. The growth rate of whiskers showed maxima against both titanium tetrachloride and methane concentrations. The growth rate decreased with a decrease in hydrogen concentration. The maximum linear growth rate observed was ∼1.2 × 10-4 1098 1184 V 3 cm/sec. The titanium carbide whiskers were found to grow preferentially in the [111] direction." @default.
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- W1984287462 date "1977-03-01" @default.
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- W1984287462 title "Growth rate of titanium carbide whiskers in chemical vapor deposition" @default.
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- W1984287462 doi "https://doi.org/10.1016/0022-0248(77)90123-3" @default.
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