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- W1984366941 abstract "Irradiation at λ = 507 and 391 nm of [Mo2(η5-C5H5)2(CO)6] in a degassed tetrahydrofuran (THF) or THF-MeOH solution containing nitrite gives [Mo(η5-C5H5)2NO] and several oxo complexes including [{Mo(η5-C5H5)(O)2}2O] in good yields. The quantum yields for the disappearance of [Mo2(η5-C5H5)2(CO)6] in the reaction with NO2− depend on the nitrite concentration, thus suggesting participation of the metal-radical intermediate in the reduction of nitrite. Reactions of [Mo2(η5-C5H5)2(CO)4] with nitrite or nitrate in the dark give the same nitrosyl and oxo complexes as above. An oxygen atom in nitrite or nitrate is mainly transferred onto the molybdenum atom both in the photochemical and the dark reactions." @default.
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- W1984366941 date "1987-09-01" @default.
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- W1984366941 title "Comparative studies of the photochemical and thermal reactivities of the molybdenum-molybdenum single bond in [Mo2(η5-C5H5)2(CO)6] and triple bond in [Mo2(η5-C5H5)2(CO)4] towards nitrite and nitrate" @default.
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- W1984366941 doi "https://doi.org/10.1016/0022-328x(87)80023-2" @default.
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