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- W1984494604 abstract "Abstract LiMg 0.08 Mn 1.92 O 4 cathode materials were prepared by a solid-state combustion synthesis at different calcination temperatures. The crystal structure was characterized by X-ray diffraction (XRD) analysis and the morphology was observed by scanning electron microscopy (SEM). All the calcined materials were identified as the spinel structure of LiMn 2 O 4 . The materials synthesized at 500 °C, 600 °C and 700 °C were single phase, while Mn 3 O 4 impurity phases can be detected in the other materials synthesized at 800 °C and 900 °C. The average particle size increased with the increase of calcination temperature. The effect of two-stage calcination temperature on the electrochemical properties of the LiMg 0.08 Mn 1.92 O 4 materials was studied by galvanostatic charge/discharge tests, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements. Results showed that the structural stability of the materials was improved due to Mg-doping. The LiMg 0.08 Mn 1.92 O 4 materials calcined at 600 °C and 700 °C demonstrated excellent electrochemical performance with an initial discharge specific capacity of 101.3 mAh g −1 and 107.6 mAh g −1 , and their capacity retention was 98.1% and 94.3% after 40 cycles at 0.2 C, respectively." @default.
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- W1984494604 date "2014-08-01" @default.
- W1984494604 modified "2023-10-12" @default.
- W1984494604 title "Study on the electrochemical performance of high-cycle LiMg0.08Mn1.92O4 cathode material prepared by a solid-state combustion synthesis" @default.
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- W1984494604 doi "https://doi.org/10.1016/j.ceramint.2014.03.077" @default.
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