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- W1984580012 abstract "By strategic combination of weak acid, mild oxidizing agent, and polar organic solvents containing millimolar concentrations of leucocyanides of certain triphenylmethane dyes, fairly broad ranges of absorbed doses of ionizing radiation can be determined. The yield of dye ions as determined by spectrophotometry can be made essentially constant with dose (i.e. linear response) from 0.01 to 30 kGy and it does not vary with dose rate upto 1011 Gy·s−1. The radiation-induced color is stable and offers fast-retrieval dosimetry if N-vinyl-2-pyrrolidone is used as solvent. Other possible polar solvents are 2-propanol, 2-methoxy ethanol, N, N-dimethyl formamide, dimethyl sulfoxide, and triethyl phosphate. Dimethyl sulfoxide is found to give the widest and most linear response. Suitable dye precursors are leucocyanides of pararosaniline, new fuchsin, hexa (hydroxyethyl) pararosaniline, crystal violet, malachite green, setoglaucine, ethyl violet, helvetia green, basic violet-14, and formyl violet. Low concentrations of carboxylic acids contribute stability to the system. Typical mild oxidizing agents are nitrobenzene, and atmospheric oxygen, or oxygen released radiolytically from the solvents. The dosimetry systems do not require high-purity of ingredients or ultracleanliness of containers, although, for reproducibility of dye yields (G-values), thoroughly purified and uniform dye derivates are recommended." @default.
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- W1984580012 date "1981-01-01" @default.
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- W1984580012 title "Liquid radiochromic dosimetry" @default.
- W1984580012 doi "https://doi.org/10.1016/0146-5724(81)90290-9" @default.
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