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- W1984591603 abstract "Abstract Dichlorocobalt(III) complexes of (2 S ,5 S ,9 S )-trimethyltriethylenetetraamine (L 1 ) and (2 S ,5 R ,9 S )-trimethyltriethylenetetraamine (L 2 ) have been prepared. Both L 1 and L 2 coordinate to the cobalt(III) ion to give three isomers: Λ- cis -α, Δ- cis -β, trans isomers for L 1 and Δ- cis -α, Δ- cis -β, trans isomers for L 2 . Each of the trans -dichloro complexes of the two ligands have been isomerized stereospecifically to the cis - α -dichloro complex in methanol, and each of the cis - α -dichloro complexes stereospecifically to the trans -diaqua complex in water. Both the geometrical and optical inversions took place at the same time in the observed stereospecific isomerizations." @default.
- W1984591603 created "2016-06-24" @default.
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- W1984591603 date "1995-12-01" @default.
- W1984591603 modified "2023-09-27" @default.
- W1984591603 title "The stereochemistry of the dichlorocobalt(III) complexes with (2S,5S,9S)- and (2S,5R,9S)-trimethyltriethylenetetraamines" @default.
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- W1984591603 doi "https://doi.org/10.1016/0277-5387(95)00184-t" @default.
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