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- W1984597503 abstract "TiO2 nano-thin films with imprinted (R)- and (S)-enantiomers of propranolol, 1,1′-bi-naphthol, and 2-(4-isobutylphenyl)-propionic acid were fabricated on quartz plates by spin-coating their solutions with Ti(O-nBu)4 in a toluene-ethanol mixture (1:1, v/v). After template removal, the imprinted films showed better binding for original templates than to the corresponding enantiomers. The assessment of template incorporation, template removal, and re-binding was conducted through UV–vis measurements. Significant enhancement of enantioselectivity was achieved by optimization of the film thickness and by heat-treatment of the imprinted films. After subtraction of non-specific binding, the optimized films provided chiral recognition with the enantioselectivity of almost 100% for (R)-propranolol and 95% for (S)-propranolol." @default.
- W1984597503 created "2016-06-24" @default.
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- W1984597503 date "2011-05-01" @default.
- W1984597503 modified "2023-10-16" @default.
- W1984597503 title "Remarkable enantioselectivity of molecularly imprinted TiO2 nano-thin films" @default.
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- W1984597503 doi "https://doi.org/10.1016/j.aca.2011.02.042" @default.
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