FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1984637344> ?p ?o ?g. }

• W1984637344 endingPage "1203" @default.
• W1984637344 startingPage "1196" @default.
• W1984637344 abstract "A series of complexes of the type trans-[Co((BA) 2 en)(amine) 2 ]ClO 4 — where (BA) 2 en is the bis(benzoylacetone)ethylenediimine dianion and the amines are morpholine (mrpln) 1, aniline (aniln) 2, benzylamine (bzlan) 3, piperidine (pprdn) 4, p-toluidine (p-toldn) 5, and pyrrolidine (prldn) 6 — has been synthesized and characterized by elemental analysis, UV–vis, 1 H NMR, and 13 C NMR spectroscopy. The crystal and molecular structure of trans-[Co((BA) 2 en)(mrpln) 2 ]ClO 4 (1) has been determined by X-ray crystallography. The electrochemical reduction of these complexes at a glassy-carbon electrode, in the potential range of 0.5 to –2.0 V (vs. Ag/AgCl), in acetonitrile solution, indicates that the first reduction potential of Co(III/II) is irreversible, which is accompanied by the dissociation of the axial amine–cobalt bonds. This potential is dependent on the pK a of the axial amines. The second reduction potential of Co(II/I) shows reversible behavior and is also independent of the axial amine pK a . These results indicate the loss of the axial amines in the first redox process and the involvement of a four-coordinate species in the second redox step.Key words: Schiff base, cobalt(III), axial amine, electrochemical properties, crystal structure." @default.
• W1984637344 created "2016-06-24" @default.
• W1984637344 creator A5014778834 @default.
• W1984637344 creator A5082270080 @default.
• W1984637344 creator A5087288005 @default.
• W1984637344 date "2002-09-01" @default.
• W1984637344 modified "2023-09-27" @default.
• W1984637344 title "Synthesis, structure, and electrochemistry of cobalt(III) complexes with bis(benzoylacetone)ethylenediimine Schiff base" @default.
• W1984637344 cites W1964743257 @default.
• W1984637344 cites W1967152759 @default.
• W1984637344 cites W1974685706 @default.
• W1984637344 cites W1983395424 @default.
• W1984637344 cites W1986888071 @default.
• W1984637344 cites W1989199714 @default.
• W1984637344 cites W1993854135 @default.
• W1984637344 cites W2007984633 @default.
• W1984637344 cites W2023114659 @default.
• W1984637344 cites W2025962054 @default.
• W1984637344 cites W2030085905 @default.
• W1984637344 cites W2048036692 @default.
• W1984637344 cites W2064954501 @default.
• W1984637344 cites W2070031786 @default.
• W1984637344 cites W2082220889 @default.
• W1984637344 cites W2086080980 @default.
• W1984637344 cites W2091912437 @default.
• W1984637344 cites W2093414622 @default.
• W1984637344 cites W2313284265 @default.
• W1984637344 cites W2316876734 @default.
• W1984637344 cites W2949067101 @default.
• W1984637344 cites W2953079496 @default.
• W1984637344 cites W4232390144 @default.
• W1984637344 doi "https://doi.org/10.1139/v02-122" @default.
• W1984637344 hasPublicationYear "2002" @default.
• W1984637344 type Work @default.
• W1984637344 sameAs 1984637344 @default.
• W1984637344 citedByCount "29" @default.
• W1984637344 countsByYear W19846373442012 @default.
• W1984637344 countsByYear W19846373442013 @default.
• W1984637344 countsByYear W19846373442014 @default.
• W1984637344 countsByYear W19846373442015 @default.
• W1984637344 countsByYear W19846373442016 @default.
• W1984637344 countsByYear W19846373442018 @default.
• W1984637344 countsByYear W19846373442021 @default.
• W1984637344 crossrefType "journal-article" @default.
• W1984637344 hasAuthorship W1984637344A5014778834 @default.
• W1984637344 hasAuthorship W1984637344A5082270080 @default.
• W1984637344 hasAuthorship W1984637344A5087288005 @default.
• W1984637344 hasConcept C115624301 @default.
• W1984637344 hasConcept C131779359 @default.
• W1984637344 hasConcept C147789679 @default.
• W1984637344 hasConcept C155647269 @default.
• W1984637344 hasConcept C17525397 @default.
• W1984637344 hasConcept C178790620 @default.
• W1984637344 hasConcept C179104552 @default.
• W1984637344 hasConcept C185592680 @default.
• W1984637344 hasConcept C188027245 @default.
• W1984637344 hasConcept C2776276205 @default.
• W1984637344 hasConcept C2776428424 @default.
• W1984637344 hasConcept C2777463227 @default.
• W1984637344 hasConcept C2779244968 @default.
• W1984637344 hasConcept C2781056017 @default.
• W1984637344 hasConcept C2781462491 @default.
• W1984637344 hasConcept C515602321 @default.
• W1984637344 hasConcept C52859227 @default.
• W1984637344 hasConcept C55904794 @default.
• W1984637344 hasConcept C8010536 @default.
• W1984637344 hasConceptScore W1984637344C115624301 @default.
• W1984637344 hasConceptScore W1984637344C131779359 @default.
• W1984637344 hasConceptScore W1984637344C147789679 @default.
• W1984637344 hasConceptScore W1984637344C155647269 @default.
• W1984637344 hasConceptScore W1984637344C17525397 @default.
• W1984637344 hasConceptScore W1984637344C178790620 @default.
• W1984637344 hasConceptScore W1984637344C179104552 @default.
• W1984637344 hasConceptScore W1984637344C185592680 @default.
• W1984637344 hasConceptScore W1984637344C188027245 @default.
• W1984637344 hasConceptScore W1984637344C2776276205 @default.
• W1984637344 hasConceptScore W1984637344C2776428424 @default.
• W1984637344 hasConceptScore W1984637344C2777463227 @default.
• W1984637344 hasConceptScore W1984637344C2779244968 @default.
• W1984637344 hasConceptScore W1984637344C2781056017 @default.
• W1984637344 hasConceptScore W1984637344C2781462491 @default.
• W1984637344 hasConceptScore W1984637344C515602321 @default.
• W1984637344 hasConceptScore W1984637344C52859227 @default.
• W1984637344 hasConceptScore W1984637344C55904794 @default.
• W1984637344 hasConceptScore W1984637344C8010536 @default.
• W1984637344 hasIssue "9" @default.
• W1984637344 hasLocation W19846373441 @default.
• W1984637344 hasOpenAccess W1984637344 @default.
• W1984637344 hasPrimaryLocation W19846373441 @default.
• W1984637344 hasRelatedWork W1962429509 @default.
• W1984637344 hasRelatedWork W1974062118 @default.
• W1984637344 hasRelatedWork W1988038603 @default.
• W1984637344 hasRelatedWork W1993517950 @default.
• W1984637344 hasRelatedWork W2047830489 @default.
• W1984637344 hasRelatedWork W2068013113 @default.
• W1984637344 hasRelatedWork W2079575973 @default.
• W1984637344 hasRelatedWork W2130211444 @default.
• W1984637344 hasRelatedWork W2949994807 @default.

• next