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- W1984646875 abstract "The rate constant for reaction of OH radical with toluene in aqueous solutions saturated with N2O or containing 0.1 M H2O2 has been determined by pulse radiolysis to be 8.1×109 l mol−1 s−1. This rate constant is comparable to the value of 7.8×109 l mol−1 s−1 for reaction with benzene determined under similar conditions. This latter rate constant provides a reference value of 1.3×109 l mol−1 s−1 with which to compare the partial rate constants for reaction of OH at the various positions of substituted aromatics. Comparison of the kinetic responses in the N2O and H2O2 systems provides a direct measure of the pseudo-first-order rate constant for reaction of O− with water as 7.9×107 s−1." @default.
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- W1984646875 date "2002-06-01" @default.
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- W1984646875 title "The rate constants for reaction of OH radicals with benzene and toluene" @default.
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