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• W1984661010 abstract "By using XRD, TG-DTA, NMR, and UV resonance Raman spectroscopy, the nature and location of vanadium species between VAPO-5 and VAPSO-5 molecular sieves were comparatively studied. It was found that different vanadium species exist in VAPO-5 and VAPSO-5 molecular sieves. Polymerized vanadium oxides and bulk V2O5 crystallites are the main vanadium species in VAPO-5 molecular sieves. However, in VAPSO-5 molecular sieves, tetrahedrally coordinated vanadium species are dominant. Namely, most of the vanadium species in VAPO-5 exist outside the framework, whereas most of the vanadium species in VAPSO-5 are incorporated into the framework. The formation of framework vanadium in VAPSO-5 molecular sieves is found to be associated essentially with the presence of framework silicon atoms." @default.
• W1984661010 created "2016-06-24" @default.
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• W1984661010 date "2002-08-10" @default.
• W1984661010 modified "2023-09-28" @default.
• W1984661010 title "Comparative Study of the Vanadium Species in VAPO-5 and VAPSO-5 Molecular Sieves" @default.
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• W1984661010 doi "https://doi.org/10.1021/jp013285q" @default.
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