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- W1984712115 abstract "The diffusion of water protons in hydrated vermiculite crystals has been studied by the pulsed magnetic-field gradient, spin-echo technique. Li+ and n-butylammonium ion-exchanged vermiculites have been swollen with water to basal spacings between the parallel silicate layers from 100 to 1030 A. In this state, self-diffusion has been studied as a function of sample orientation and diffusion time (from 3 to 11 msec). Diffusion is seen to be anisotropic with the behavior perpendicular to the layers differing from that parallel to the layers. Parallel to the layers, the protons move freely as if in liquid water except for a small fraction affected by buckled layers. Perpendicular to the layers, as many as half the protons behave as if in liquid water; presumably they are moving in large cracks in the lattice. The remainder of the protons are interpreted as confined to “pores” of average sizes ranging from 200 to 1800 A (relative to the unswollen lattice). Our estimates of the “pore” size are consistent with electron microscope studies by other workers. Because of the restrictions afforded by these “pores”, it is necessary to interpret the data in terms of a model which does not follow Fick's law. There is evidence of morphological changes attending swelling. It is determined that for the systems studied, Young River, West Australia vermiculite had the least water in “pores,” whereas Libby, Montana hydrobiotite contained the most buckles. Kenya vermiculite was also studied. Detailed studies of T1 and T2 indidicate single relaxation times which are anisotropic. The longer times are always observed with the vermiculite layers parallel to the magnetic field; increasing the basal spacing also increases the relaxation times. The relaxation anisotropy is attributed to anisotropic paramagnetism of the iron-filled vermiculite layers." @default.
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- W1984712115 date "1968-03-01" @default.
- W1984712115 modified "2023-10-17" @default.
- W1984712115 title "Restricted, anisotropic diffusion and anisotropic nuclear spin relaxation of protons in hydrated vermiculite crystals" @default.
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- W1984712115 doi "https://doi.org/10.1016/0021-9797(68)90232-4" @default.
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