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- W1984756554 abstract "Although the properties of a glass depend to some extent upon its thermal history, the view is expressed that fairly satisfactory thermodynamic data can be obtained for well-annealed glasses. In the present study the difference between the heat contents of glucose glass and α-crystals has been determined calorimetrically at 20°C and with the aid of this result the corresponding differences in entropy and free energy have also been computed. The value for this last quantity is ΔF°293 = 1670 cal. per mol. Solubility measurements have been made for glucose α-crystals and glass in methyl, ethyl and isopropyl alcohols at 20°. The free energy values thereby obtained for the conversion of α-crystals into glassy glucose are in good agreement with the preceding value derived from the thermal data." @default.
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- W1984756554 date "1934-09-01" @default.
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- W1984756554 title "Studies on Glass. XI. Some Thermodynamic Relations of Glassy and Alpha-Crystalline Glucose" @default.
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- W1984756554 doi "https://doi.org/10.1063/1.1749540" @default.
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