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- W1984902145 abstract "The reaction of 5-nitroisophthalic acid (H 2 NIA) with Gd(NO 3 ) 3 ·6H 2 O in DMF afforded three new metal-organic frameworks: [Gd(NIA) 1.5 (DMF) 2 ]·DMF (I), [Gd 2 (NIA) 3 (DMF) 4 ]· x H 2 O (II) and [Gd 4 (NIA) 6 (DMF) 5.5 (H 2 O) 3 ]·4DMF·H 2 O (III). These compounds can be prepared through a variety of methods. Compounds (I) and (II) are more reproducibly formed than compound (III). Network analysis revealed (I) to have a (4 12 .6 3 )- pcu topology, while (II) displays a (4 2 .8 4 )(4 2 .8 4 )- pts topology. Compound (III) was found to present the uncommon 4,5,6T11 topological net, which combines aspects of both the pcu and pts topologies. The short symbol of this net is (4 4 .6 2 )(4 6 .6 4 ) 2 (4 8 .6 6 .8)." @default.
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- W1984902145 date "2012-08-17" @default.
- W1984902145 modified "2023-10-18" @default.
- W1984902145 title "Topological studies of three related metal-organic frameworks of Gd<sup>III</sup> and 5-nitroisophthalate" @default.
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- W1984902145 doi "https://doi.org/10.1107/s0108768112032053" @default.
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