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- W1984920382 abstract "The exothermic effects observed on wetting pectins with water and aliphatic alcohols were studied using a microcalorimeter. The heat released on wetting 1 g pectin with water was found to be 171 ± 7·5 J g−1. It was experimentally established that 1 g of dry pectin exothermically bonded up to 0·57 g of water. By using the Gibbs-Helmholtz-Young equation which relates the heat released by wetting to the area of the wetted surface, it was estimated that the surface accessible to water in 1 g of pectin was 1·46 × 103 m2 g−1. The heat of hydration was independent of the degree of esterification of the pectin. The experimental results revealed that there were about six molecules of energetically bonded water per monomer unit of pectin. A specific interaction between methanol and the methoxyl groups of pectin was observed on wetting pectins with methanol and dependence was established between the released heat and the degree of esterification. No similar dependence was reported for the remaining aliphatic alcohols." @default.
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- W1984920382 date "1985-01-01" @default.
- W1984920382 modified "2023-09-25" @default.
- W1984920382 title "Microcalorimetric studies on the lyophilic properties of pectic substances" @default.
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- W1984920382 doi "https://doi.org/10.1016/0144-8617(85)90017-7" @default.
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