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- W1984939847 abstract "X-ray absorption-edge measurements were used to investigate the electronic configuration of cerium in different series of amorphous alloys, namely the Ce-Si alloys and the intermetallic Ce-Ni and Ce-Co alloys. The effect of structural disorder is evaluated from a comparison of our data on amorphous alloys with those obtained for compositionally related crystalline compounds. While the ${L}_{mathrm{III}}$ absorption edge for ${mathrm{CeSi}}_{2}$ exhibits a weak valence anomaly, the trivalent configuration of cerium is stabilized by the topological disorder in amorphous alloys over the whole concentration range we investigated (0.10ensuremath{le}xensuremath{le}0.80). In contrast, strong valence anomalies on cerium are retained in amorphous Ce-Ni and Ce-Co alloys without any significant effect attributable to amorphicity." @default.
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- W1984939847 date "1986-08-15" @default.
- W1984939847 modified "2023-10-17" @default.
- W1984939847 title "Electronic configuration of cerium in amorphous alloys investigated by x-ray absorption spectroscopy" @default.
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- W1984939847 doi "https://doi.org/10.1103/physrevb.34.2176" @default.
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