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- W1984945519 abstract "Three new binuclear copper(I) complexes, [Cu2(paa)(dppm)2](BF4)2 (1), [Cu2(N^N^O)(dppm)2]BF4 (2), and [Cu2(N^C^N)(dppm)2](BF4)2 (3), were prepared with bridging or chelating pyridine-2-carbaldehyde azine (paa or N^N-N^N), 2,4-dimethyl-7-hydroxyl-1,8-naphthyridine (N^N^OH), 1-methyl-3,5-di(2-pyridyl)benzene (N^C^N), and bis(diphenylphosphino)methane (dppm) ligands and their structures were determined by X-ray crystal analysis. The structural analysis revealed that coppers in the complexes are three- and four-coordinate and N^N-N^N adopts N,N chelating and bridging coordination modes while N^N^OH, N^C^N and dppm afforded only a bridging model. The two metal centers approach closely with copper(I)–copper(I) distances of 2.7811–3.420 Å. Intense solid-state emission centered at 490 nm was observed for 1." @default.
- W1984945519 created "2016-06-24" @default.
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- W1984945519 date "2010-07-16" @default.
- W1984945519 modified "2023-10-17" @default.
- W1984945519 title "Synthesis, characterization, and spectroscopic properties of binuclear copper(I) complexes with N^N-N^N, N^N^OH, N^C^N, and phosphine ligands" @default.
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- W1984945519 doi "https://doi.org/10.1080/00958972.2010.502965" @default.
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