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- W1984984976 abstract "Abstract As a two‐dimensional material, molybdenum disulfide (MoS 2 ) has drawn wide attention due to its fascinating properties and exciting application prospects. However, in order to access these properties, which lie within single‐ or few‐layer nanosheets, the inter‐sheet van der Waals interactions within the bulk material must be adequately disrupted to exfoliate MoS 2 to atomic thicknesses. The hitch with most current exfoliation methods, though, is that they employ expensive, exotic, or environmentally incompatible methods that suffer poor scalability and poor reproducibility, producing weakly stabilized sheets that retro‐aggregate. These pitfalls render many current approaches unsuitable for the development of large‐scale devices and nanocomposites, thereby making cheaper, more benign alternatives highly sought after. Herein, we present the sonication‐assisted aqueous phase exfoliation of bulk MoS 2 into dispersed single‐ or few‐layer nanosheets using popular culinary hydrocolloids, including guar gum (GG), tannic acid (TA), and xanthan gum (XG). These green agents are commercially available, inexpensive, and environmentally friendly substances and act as good dispersing and exfoliating agents. Under optimized exfoliation conditions, dispersed solution concentrations of 0.24, 0.15, and 0.06 mg mL −1 were achieved for MoS 2 ‐GG, MoS 2 ‐TA, and MoS 2 ‐XG, respectively. In addition, the sterically stabilized nanosheets were successfully decorated with gold nanoparticles via an in situ reduction by the hydrocolloids to yield plasmonic nanocomposites exhibiting excellent catalytic activity in 4‐nitrophenol reduction." @default.
- W1984984976 created "2016-06-24" @default.
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- W1984984976 date "2015-05-20" @default.
- W1984984976 modified "2023-10-14" @default.
- W1984984976 title "Kitchen-Inspired Nanochemistry: Dispersion, Exfoliation, and Hybridization of Functional MoS<sub>2</sub>Nanosheets Using Culinary Hydrocolloids" @default.
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- W1984984976 doi "https://doi.org/10.1002/cnma.201500022" @default.
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