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• W1985079945 abstract "The molecular interactions have been studied in the ternary systems of phenol with three structurally different aromatic aldehydes, viz., benzaldehyde, cinnamaldehyde and salicylaldehyde in n-hexane medium, through the behavior of measured ultrasonic velocity ‘u’, density ‘ρ’, dynamic viscosity ‘η’ and the calculated acoustic parameters at 303.15 K and at atmospheric pressure. Excess thermo acoustic parameters reveal the existence of hydrogen bonded complexes between aldehydes and phenol. The variation of the excess parameters both in sign and magnitude within the range of concentration investigated is also discussed in terms of structural aspect and functional groups of the components involved. The existence of solute interactions is also confirmed through electronic absorption spectra with Benesi–Hildebrand theory at 303.15 K. The formation constants of the donor and acceptor complexes determined both by spectroscopic and ultrasonic methods are comparable and follow similar trend. The trend in the formation constants is discussed based on structures of the component molecules in terms of field effects." @default.
• W1985079945 created "2016-06-24" @default.
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• W1985079945 date "2013-03-01" @default.
• W1985079945 modified "2023-09-27" @default.
• W1985079945 title "Spectroscopic and ultrasonic studies on the hydrogen bonded complexes of aromatic aldehydes with phenol in hexane medium" @default.
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• W1985079945 doi "https://doi.org/10.1016/j.molliq.2012.12.022" @default.
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