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- W1985107958 abstract "In situ γ-irradiation has been found to enhance the activity of Ru/molecular sieve and Ru/alumina catalysts for the CO2 methanation reaction in the temperature range 400–600 K. The extent of radiation enhancement in catalytic activity was inversely related to temperature. The activation energy for the formation of CH4 from 2% CO2 in H2 was reduced in the presence of radiation from 13.8 to 7.7 kcal mole−1 for Ru/alumina and from 7.3 to 4.2 kcal mole−1 for Ru/molecular sieve. The results indicate that γ-irradiation gives rise to energy storage in support materials. It is suggested that the energy released on thermal stimulation weakens the metal-CO2 bonds resulting in an accelerated rate of reduction of CO2 to active carbon and its subsequent methanation." @default.
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- W1985107958 date "1980-11-01" @default.
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- W1985107958 title "Effect of $gamma;-irradiation on methanation of carbon dioxide over supported Ru catalysts" @default.
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- W1985107958 doi "https://doi.org/10.1016/0021-9517(80)90012-3" @default.
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