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- W1985156641 abstract "The radiolysis of deoxygenated aqueous solutions of Ru(NH3)5NO3+ and Fe(CN)5NO2− in the presence of organic compounds (RH) generates alkylnitroso complexes of the form Ru(NH3)5N(O)R2+ and Fe(CN)5N(O)R3− where RH = tert-butyl alcohol, tert-butyl amine, N,N-dimethylacetamide, α-aminoisobutyric acid, pivalic acid, and α-hydroxyisobutyric acid. The products form from the rapid combination of the β-carbon radical derived from the reaction of the organic compound with OH radicals (OH + RH → R· + H2O) and the one-electron reduced metal complex formed by interaction with eaq−: Ru(NH3)5NO3+ + eaq− → Ru(NH3)5NO2+; Fe(CN)5NO2− + eaq− → Fe(CN)5NO3−. The alkylnitroso complexes are moderately O2-insensitive but display varying degrees of thermal stability. Stability permitting, these complexes have been characterized by ion-exchange chromatography and UV-vis-IR spectroscopy. The green ruthenium complexes exhibit λmax 740 and 342 nm (ϵ 22 and 4.5 × 103 M−1 cm−1, respectively) and νNO in the 1365–1405 cm−1 region. The less stable red iron analogues absorb at 475 and ∼ 250 nm (ϵ 5.0 × 103 and ∼ 9 × 103 M−1 cm−1, respectively)." @default.
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- W1985156641 date "1979-01-01" @default.
- W1985156641 modified "2023-10-17" @default.
- W1985156641 title "Radiation synthesis of iron(II) and ruthenium(II) alkylnitroso complexes" @default.
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- W1985156641 doi "https://doi.org/10.1016/0022-1902(79)80432-7" @default.
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