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- W1985171907 abstract "Pure rotational transitions of a new carbon-chain radical CCCF in a supersonic jet have been observed for the first time using a Fourier-transform microwave spectrometer with a pulsed-discharge nozzle. The radical was produced by a pulsed electric discharge in a C2H2 and CF4 mixture diluted to 0.1% and 0.1% with Ne, respectively. Rotational transitions with spin and hyperfine splittings have been observed in the region from 9.1 GHz for NKaKc=101−000 to 27.3 GHz for NKaKc=303−202. The rotational constant, the spin-rotation interaction constant, and the hyperfine coupling constants due to the F nucleus have been precisely determined from the least-squares analysis, yielding B¯=4555.8043(44), γeff=−7.105(16), bF,eff=368(19), and ceff=−284.832(61) MHz. The determined molecular constants were compared with those obtained from high-level ab initio calculations and concluded that the CCCF radical has a bent ground state X̃A2′." @default.
- W1985171907 created "2016-06-24" @default.
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- W1985171907 creator A5070501990 @default.
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- W1985171907 date "2009-04-22" @default.
- W1985171907 modified "2023-10-04" @default.
- W1985171907 title "Pure rotational spectra of the CCCF radical" @default.
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- W1985171907 doi "https://doi.org/10.1063/1.3120444" @default.
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