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• W1985181156 endingPage "618" @default.
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• W1985181156 abstract "The novel transition metal saccharinato complexes of N-(2-hydroxyethyl)-ethylendiamine (HydEt-en) have been synthesized and characterized by elemental analyses, magnetic moments, UV-Vis and IR spectra. Coordination behaviour of HydEt-en has been studied. The Mn(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) form mononuclear complexes, while the Fe(II) and Co(II) complexes are dimeric. The crystal structures of the [Cu(sac)2(HydEt-en)2] and [Cd(sac)2(HydEt-en)2] complexes, where sac is the deprotonated form of saccharin, were determined by x-ray diffraction. The metal ions are octahedrally coordinated by these ligands. The amine ligand acts as a bidentate N-donor ligand and its ethanol group is not involved in coordination. The sac ions coordinate through the deprotonated N as a monodentate ligand. The NH and OH groups of the amine ligand are involved in intra- and intermolecular hydrogen bonding with the carbonyl and sulphonyl oxygens of the sac ions to form a three-dimensional infinite network." @default.
• W1985181156 created "2016-06-24" @default.
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• W1985181156 date "2002-01-01" @default.
• W1985181156 modified "2023-10-12" @default.
• W1985181156 title "Metal Complexes of Saccharin with the <i>N</i>-(2-hydroxyethyl)-ethylenediamine Ligand: Synthesis, Characterization and Spectroscopic Examination. Crystal Structures of <i>trans- Bis</i>(Saccharinato)<i>Bis</i>{<i>N</i>-(2-hydroxyethyl)-Ethylenediamine} copper(II) and Cadmium(II)" @default.
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• W1985181156 doi "https://doi.org/10.1080/00958970290027471" @default.
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