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• W1985203145 abstract "A Cu/ceria/alumina catalyst has been tested for the water–gas shift reaction under fuel reformer conditions for fuel cell applications. These catalysts do not need any reduction before use and are non-pyrophoric. However, their activity is significantly lower than a Cu/Zn/Al catalyst. A detailed kinetic analysis shows that the data can be described by a two-step redox model and that ceria lowers the activation barrier of the water dissociation. The lower activity of the Cu/Ce/Al catalyst compared to the Cu/Zn/Al is due to the lower copper surface area of the former one. The kinetic analysis includes a rigorous procedure based on an analysis of the Jacobian matrix in order to eliminate non-influential parameters from the rate-equations." @default.
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• W1985203145 date "2007-09-01" @default.
• W1985203145 modified "2023-10-17" @default.
• W1985203145 title "Kinetic modelling of CO conversion over a Cu/ceria catalyst" @default.
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• W1985203145 doi "https://doi.org/10.1016/j.ces.2007.02.030" @default.
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