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- W1985204029 abstract "Abstract Reaction of [MgCl2(THF)2] with [NBu4][BF4] yields the compounds [NBu4][MgCl4] (IV) and [Mg(THF)6][BF4]2 (V). After addition of dioxane the reaction equilibrium shifts in the opposite direction. The formation of [MgCl2(C4H8O2)2] in solution does not require the presence of MgCl2. This compound may be formed in the reaction of dioxane with the ionic or molecular species formed by the magnesium atom in solution. The [NBu4][BF4] salt also reacts with the Grignard reagent to produce compound IV which confirms that there is a new equilibrium between [Mg(R)X(THF)n] and [MgR2(THF)2], [MgCl4]2− and [Mg(THF)6]2+. Bis(tetrahydrofuran)magnesium dichloride, because of its reactivity is only stable in Grignard reagent. For that reason the composition of the Grignard reagent in solution is best described as an equilibrium between [Mg(R)X(THF)n] and [(THF)4Mg(μ-Cl)2MgR2] and [RMg2(μ-Cl)3(THF)5] rather than as a Schlenk equilibrium." @default.
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- W1985204029 date "1987-10-01" @default.
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- W1985204029 title "Influence of MgCl2 on Grignard reagent composition in tetrahydrofuran. III" @default.
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- W1985204029 doi "https://doi.org/10.1016/0022-328x(87)85090-8" @default.
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