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• W1985217812 abstract "Abstract The rates of dissociation of Ferroin, tris-(1,10-phenanthroline)iron(II) in acidic hydrochloric solutions and within Nafion ® membranes (H + and Na + forms) were determined at 25°C and were found to be first order, acid independent reactions. The rate determining step for both solution and membrane media involved the detachment of the first 1,10-phenanthroline ligand with subsequent rapid loss of the remaining two ligands. Values of the averaged rate constants of the rate determining reaction in solutions and in the Nafion ® membranes at constant ionic strength were 2.68×10 −3 and 3.82×10 −3  min −1 , respectively, the difference being due to the steric influence of the membrane. These results will be utilised in overcoming stability problems encountered in a recently developed optical redox sensor based on Ferroin immobilised within a Nafion ® membrane." @default.
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• W1985217812 date "1999-08-01" @default.
• W1985217812 modified "2023-09-26" @default.
• W1985217812 title "Dissociation of Ferroin in acidic solutions and Nafion® membranes" @default.
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• W1985217812 doi "https://doi.org/10.1016/s0003-2670(99)00328-1" @default.
• W1985217812 hasPublicationYear "1999" @default.
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