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- W1985241206 endingPage "1458" @default.
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- W1985241206 abstract "Readily available chiral thioureas derived from cyclohexane-1,2-diamine were prepared and found to be highly effective organocatalysts for the conjugate addition of aldehydes and ketones to nitroalkenes. Excellent enantioselectivities and yields were obtained for a variety of aryl and heteroaryl nitroalkenes. The base additives are essential for good yields and excellent enantioselectivities in this transformation. Based on new experimental evidence, a modified catalytic mechanism was proposed to rationalize the important role of the base additives." @default.
- W1985241206 created "2016-06-24" @default.
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- W1985241206 date "2009-07-01" @default.
- W1985241206 modified "2023-10-17" @default.
- W1985241206 title "Asymmetric conjugate addition of carbonyl compounds to nitroalkenes catalyzed by chiral bifunctional thioureas" @default.
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- W1985241206 doi "https://doi.org/10.1016/j.tetasy.2009.06.003" @default.
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