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- W1985246359 abstract "The present work reports the synthesis and free radical polymerization of 4-(2-methacryloyloxy)ethyloxyacetanilide (MOEA), an acrylic monomer derived from paracetamol (4-hydroxyacetanilide), a non-prescription analgesic and antipyretic drug that in recent years has become an increasingly popular substitute for aspirin. The monomer prepared (MOEA) can be also considered an acrylic derivative of phenacetin (4-ethoxyacetanilide) whose major metabolite in the living body is paracetamol. The radical polymerization of MOEA has been carried out in solution of DMF, initiated by AIBN at temperatures in the range 50–140°C. The kinetic behaviour indicates that this compound presents a ceiling temperature of polymerization (Tc) of about 175°C in standard conditions (|M| = 1 mol/l). The results obtained are compared with those of the free radical of 4-methacryloyloxyacetanilide (MOA) studied previously. Both acrylic monomers differ only in the presence of an oxyethylenic spacer group in MOEA, which raises the Tc of MOEA by about 38°C with respect to that of MOA (Tc=137°C)." @default.
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- W1985246359 date "1990-01-01" @default.
- W1985246359 modified "2023-10-18" @default.
- W1985246359 title "Polymers with pharmacological activity: 2. Synthesis and free radical polymerization of an acrylic derivative of phenacetin" @default.
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- W1985246359 doi "https://doi.org/10.1016/0032-3861(90)90369-a" @default.
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