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- W1985278876 abstract "Abstract A series of seven fast‐biodegrading aliphatic polyesters were prepared from 1,3‐propanediol and aliphatic diacids with increasing number of methylene units ( x ). Melting points decreased from PPSu to PPAd and then increased again to PPAz and PPSeb. Crystallization rates and thermal stability increased steadily with increasing x . Glass transition temperatures decreased steadily to PPPim and subsequently increased. Enzymatic degradation of the polymers in the presence of a mixture of Rhizopus delemar and Pseudomonas cepacia lipases was much faster than that of poly( ε ‐caprolactone). All the polyester specimens were almost disintegrated within 36 h. PPSub exhibited the fastest enzymatic hydrolysis rates, PPAd and PPSuc the slowest. magnified image" @default.
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- W1985278876 date "2008-07-31" @default.
- W1985278876 modified "2023-10-16" @default.
- W1985278876 title "Correlation between Chemical and Solid-State Structures and Enzymatic Hydrolysis in Novel Biodegradable Polyesters. The Case of Poly<b>(</b>propylene alkanedicarboxylate<b>)</b>s" @default.
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- W1985278876 doi "https://doi.org/10.1002/mabi.200800035" @default.
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