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- W1985280335 abstract "Abstract When 8-acetoxy-2,6-dimethyl-9-phenylthio-2,6-nonadiene was successively treated with TMSOTf and Et 3 N in CH 2 Cl 2 at room temperature, an alkylative cyclization proceeded with high diastereoselectivity to give cis -4-isopropenyl-1-methyl-3-phenylthiomethyl-1-cyclohexene. A 1 H NMR study of the reaction suggested that a cyclic sulfonium ion was formed as an intermediate. The sulfenyl group-assisted reaction could he applied for the cyclization of secondary alcohol derivatives." @default.
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- W1985280335 date "1993-10-01" @default.
- W1985280335 modified "2023-09-22" @default.
- W1985280335 title "Highly stereoselective cationic cyclization assisted by a sulfenyl group" @default.
- W1985280335 cites W1984134980 @default.
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- W1985280335 doi "https://doi.org/10.1016/s0040-4039(00)61599-x" @default.
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