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• W1985296307 endingPage "1710" @default.
• W1985296307 startingPage "1705" @default.
• W1985296307 abstract "Abstract Zincocene Cp* 2 Zn reacts with carbodiimides C(N R ) 2 with insertion into the Zn–Cp* bond and formation of [(Cp*C(N R ) 2 ] 2 Zn [ R = Et ( 1 ), i Pr ( 2 ), Cy ( 3 )]. In addition, the reaction of Cp* 2 Zn with CS 2 under dry conditions gives (Cp*CS 2 ) 2 Zn ( 4 ), whereas in the presence of a small amount of water [Zn 4 (μ 4 ‐O)(S 2 CCp*) 6 ] ( 5 ) is obtained. Compounds 1 – 4 were characterized by NMR ( 1 H, 13 C) and IR spectroscopy as well as elemental analysis and single‐crystal X‐ray diffraction ( 2 – 4 , 5 of poor quality). The solid‐state structure of 5 is comparable to the carboxylate complex previously obtained from the reaction of Cp* 2 Zn with CO 2 ." @default.
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• W1985296307 date "2012-04-26" @default.
• W1985296307 modified "2023-10-09" @default.
• W1985296307 title "Insertion Reactions of Heterocumulenes with Zincocene Cp*₂Zn" @default.
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• W1985296307 doi "https://doi.org/10.1002/zaac.201200061" @default.
• W1985296307 hasPublicationYear "2012" @default.
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