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• W1985310887 endingPage "1038" @default.
• W1985310887 startingPage "1032" @default.
• W1985310887 abstract "The rotational spectra of two isotopologues of a 1:1 difluoromethane–dichloromethane complex have been investigated by pulsed-jet Fourier-transform microwave spectroscopy. The assigned (most stable) isomer has Cs symmetry and it displays a network of two CH⋅⋅⋅ClC and one CH⋅⋅⋅FC weak hydrogen bonds, thus suggesting that the former interactions are stronger. The hyperfine structures owing to 35Cl (or 37Cl) quadrupolar effects have been fully resolved, thus leading to an accurate determination of the three diagonal (χgg; g=a, b, c) and the three mixed quadrupole coupling constants (χgg′; g, g′=a, b, c; g≠g′). Information on the structural parameters of the hydrogen bonds has been obtained. The dissociation energy of the complex has been estimated to be 7.6 kJ mol−1." @default.
• W1985310887 created "2016-06-24" @default.
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• W1985310887 date "2014-02-26" @default.
• W1985310887 modified "2023-10-09" @default.
• W1985310887 title "Interactions between Freons: A Rotational Study of CH₂F₂-CH₂Cl₂" @default.
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• W1985310887 doi "https://doi.org/10.1002/asia.201301722" @default.
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