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- W1985339770 abstract "Combustion of o-, m-, and p-nitroazidobenzene; 2,4-, 2,6-, 3,5-dinitroazidobenzene; 4,6-dinitro-2-azidophenol; 2,4,6-trinitroazidobenzene; 4,6-dinitro-1,3-diazidobenzene; 2,4,6-trinitro-1,3,5-triazidobenzene, and some furoxans formed on decomposition of azides was studied in the 0.1–36-MPa pressure range. The temperature profile in the combustion wave of benzofuroxan and isomers of mononitroazidobenzene was measured using 5-μm-thick Π-shaped tungsten-rhenium tape thermocouples. The effect of the initial temperature on the burning rate of p-nitroazidobenzene was studied. It is shown that the structure of aromatic nitroazides exerts a decisive influence on the burning rate, which is seen most clearly from the burning rates of isomers. Heat release in the condensed phase is shown to play a dominant role in the combustion of mononitroazidobenzenes. The oxygen in the nitro group of the nitroazidobenzene molecule does not take part in the reactions determining the burning rate of the compound. The measured temperatures of the products of combustion of mononitroazidobenzenes and benzofuroxan are 300–450 K lower than the calculated values. A suggestion is made that this is due to the fact that one of the nitrogen atoms of the azide group or of the furoxan ring remains in the combustion products in the form of the energetic nitrile group. On the basis of the results of thermocouple-aided measurements, a scheme of transformation of mononitroazidobenzene and benzofuroxan in the combustion wave is proposed." @default.
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- W1985339770 date "1991-11-01" @default.
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- W1985339770 title "Combustion of nitro derivatives of azidobenzenes and benzofuroxans" @default.
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- W1985339770 doi "https://doi.org/10.1016/0010-2180(91)90162-5" @default.
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