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- W1985339910 abstract "Abstract Four Schiff base ligands, salabza-H2 = N,N′-bis(salicylidene)-2-aminobenzylamine, were synthesized by condensation of one mole of 2-aminobenzylamine and two moles of salicylaldehyde and/or two moles of substituted salicylaldehyde (5-OMe, 5-Br, 5-NO2). All the four Schiff bases and their Mn(II), Co(II), Cu(II) and Zn(II) complexes are characterized by UV-Vis, FT-IR, 1H NMR spectroscopy, mass spectrometry and elemental analysis. The formation constants and the Gibbs free energies were measured spectrophotometrically for 1:1 complexes in methanol in constant ionic strength (I = 0.1 mol dm−3 NaClO4) and at 25°C. The data refinement was carried out with the SQUAD program. The trend of formation constants of H2L1 with M(II) follows the order: Mn(II) (3.97) Also, the trend of formation constants of ligand toward a given metal (for example Mn) is as follows: H2L1 (p-OMe) (3.97) > H2L2 (p-H) (3.65) > H2L3 (p-Br) (3.37) > H2L4 (p-NO2) (3.04)" @default.
- W1985339910 created "2016-06-24" @default.
- W1985339910 creator A5015009681 @default.
- W1985339910 creator A5017502540 @default.
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- W1985339910 date "2010-04-01" @default.
- W1985339910 modified "2023-09-25" @default.
- W1985339910 title "Metallation of tetradentate N2O2 Schiff base with Mn(II), Co(II), Cu(II) and Zn(II): synthesis, characterization and formation constants measurement" @default.
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- W1985339910 doi "https://doi.org/10.2478/s11532-009-0147-3" @default.
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