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• W1985346043 abstract "The migration of endocrine-disrupting di-(2-ethylhexyl) phthalate (DEHP) poses a serious threat to public health and the environment. In this study, we successfully prepared a plasticizer with reduced DEHP migration by directly incorporating 2,3,6-per-O-benzoyl-β-cyclodextrin (Bz-β-CD) into DEHP. Bz-β-CD was prepared by esterification between the hydroxyl groups of β-CD and benzoyl chloride. The presence of this cyclodextrin is expected to facilitate formation of stable complexes through π−π association with DEHP molecules. The flexible PVC was prepared with a gelation−fusion process that uses the prepared migration-resistant plasticizer, and its properties (flexibility, thermal stability, and clarity) were evaluated by carrying out DSC and tensile testing, TGA, and haze testing, respectively. No significant changes in the physical properties of the flexible PVC were observed when Bz-β-CD was added. DEHP migration tests were carried out for the flexible PVC according to the ISO 3826:1993(E) test method, and the quantity of migrated DEHP was then determined with UV−vis spectroscopy. It was found that the addition of Bz-β-CD decreases the levels of DEHP migration from the flexible PVC samples by almost 40%. We investigated the molecular interaction between Bz-β-CD and DEHP using molecular mechanics simulations, and we conclude that this reduction in DEHP migration is due to the formation of stabilized π−π attractive association and inclusion complexes of Bz-β-CD and DEHP in flexible PVC." @default.
• W1985346043 created "2016-06-24" @default.
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• W1985346043 date "2008-08-27" @default.
• W1985346043 modified "2023-10-16" @default.
• W1985346043 title "Reduced Migration from Flexible Poly(vinyl chloride) of a Plasticizer Containing β-Cyclodextrin Derivative" @default.
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• W1985346043 doi "https://doi.org/10.1021/es800895x" @default.
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