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- W1985355059 abstract "The chemoselective reactions of 1,n-dicarbonyl compounds with allyl halides using indium metal were investigated. α-Ketoesters such as ethyl pyruvate, ethyl 3-methyl-2-oxobutyrate and ethyl benzoylformate reacted with a variety of allyl halides in the presence of indium to afford hydroxy unsaturated carbonyl compounds in good to excellent yields in MeOH/HCl at 25 °C. For the allyl bromide, the presence of various substituents at the α or γposition exhibited little effects on both the reaction rates and yields. Ethyl acetoacetate or ethyl levulinate was treated with allylindium reagent to give hydroxy unsaturated carbonyl compounds in good yield. These results mean that both reactivity and selectivity are independent of the distance between carbonyl groups. 2,3-Butanedione or 1-phenyl-1,2-propanedione reacted with allylindium to produce monoallylation product as major compound." @default.
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- W1985355059 date "2010-05-21" @default.
- W1985355059 modified "2023-09-25" @default.
- W1985355059 title "ChemInform Abstract: A Convenient Allylation of 1,n-Dicarbonyl Compounds Using Organoindium Reagents." @default.
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- W1985355059 doi "https://doi.org/10.1002/chin.200228117" @default.
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