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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985360331> ?p ?o ?g. }

• W1985360331 endingPage "14937" @default.
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• W1985360331 abstract "A nickel-catalyzed reductive carboxylation of styrenes using CO2 has been developed. The reaction proceeds under mild conditions using diethylzinc as the reductant. Preliminary data suggests the mechanism involves two discrete nickel-mediated catalytic cycles, the first involving a catalyzed hydrozincation of the alkene followed by a second, slower nickel-catalyzed carboxylation of the in situ formed organozinc reagent. Importantly, the catalyst system is very robust and will fixate CO2 in good yield even if exposed to only an equimolar amount introduced into the headspace above the reaction." @default.
• W1985360331 created "2016-06-24" @default.
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• W1985360331 date "2008-10-17" @default.
• W1985360331 modified "2023-10-06" @default.
• W1985360331 title "Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO₂" @default.
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• W1985360331 doi "https://doi.org/10.1021/ja8062925" @default.
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