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- W1985394750 abstract "The new mixed tetranuclear carbonyls Co3Rh(CO)12, Co2Rh2(CO)12, Co2Ir2(CO)12, Rh3Ir(CO)12 and Rh2Ir2(CO)12 are easily synthesised by reacting tetracarbonylmetallate anions with halocarbonyls or with metallic cations in aqueous solution. Infrared spectra of all these compounds reveal the presence of both terminal and bridging carbonyl groups, in most cases consistent with a Co4(CO)12-Rh4(CO)12 like structure. Thermal stability decreases as the rhodium content increases, as shown by the facile redistribution to tetranuclear species containing less rhodium and to hexanuclear species, such as Co2Rh4(CO)16. Mass spectra are generally complicated, except in the case of Co2Ir2(CO)12, and parallel the thermal stability. All compounds containing cobalt react readily with Lewis bases. Preliminary X-ray data for Co2Rh2(CO)12, Co2Ir2(CO)12 and Co2Rh4(CO)16 are also reported." @default.
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- W1985394750 date "1973-10-01" @default.
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- W1985394750 title "New mixed tetranuclear metal carbonyls of group VIIIB" @default.
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- W1985394750 doi "https://doi.org/10.1016/s0022-328x(00)95055-1" @default.
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