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- W1985444949 abstract "The syntheses of [M(HMPA)6](ClO4)3 (HMPA = hexamethylphosphoramide; M = Ln, Sc, Y) from acetonitrile and of M(HMPA)4(ClO4)3 from ethanol are described. Combined Raman and infrared spectroscopy show that the first series contains non-coordinated perchlorate only. In the second series, the amount of ionic perchlorate diminishes from the lighter to the heavier lanthanides, while bidentate perchlorate coordination is progressively replaced by monodentate perchlorate coordination." @default.
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- W1985444949 date "1975-01-01" @default.
- W1985444949 modified "2023-09-26" @default.
- W1985444949 title "Raman and infrared study of hexamethylphosphoramide complexes of lanthanide perchlorates" @default.
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- W1985444949 doi "https://doi.org/10.1016/s0020-1693(00)93904-5" @default.
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