FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985446938> ?p ?o ?g. }

• W1985446938 endingPage "8238" @default.
• W1985446938 startingPage "8238" @default.
• W1985446938 abstract "The metathetical reaction of [Li(TMEDA)][HC(PPh(2)Se)(2)] ([Li(TMEDA)]1) with TlOEt in a 1:1 molar ratio afforded a homoleptic Tl(I) complex as an adduct with LiOEt, Tl[HC(PPh(2)Se)(2)]·LiOEt (7), which undergoes selenium-proton exchange upon mild heating (60 °C) to give the mixed-valent Tl(I)/Tl(III) complex {[Tl][Tl{(Se)C(PPh(2)Se)(2)}(2)]}(∞) (8). Treatment of TlOEt with [Li(TMEDA)](2)[(SPh(2)P)(2)CE'E'C(PPh(2)S)(2)] (3b, E' = S; 3c, E' = Se) in a 2:1 molar ratio produced the binuclear Tl(i)/Tl(i) complexes Tl(2)[(SPh(2)P)(2)CE'E'C(PPh(2)S)(2)] (9b, E' = S; 9c, E' = Se), respectively. Selenium-proton exchange also occurred upon addition of [Li(TMEDA)]1 to InCl(3) to yield the heteroleptic complex (TMEDA)InCl[(Se)C(PPh(2)Se)(2)] (10a). Other examples of this class of In(III) complex, (TMEDA)InCl[(E')C(PPh(2)E)(2)] (10b, E = E' = S; 10c, E = S, E' = Se) were obtained via metathesis of InCl(3) with [Li(TMEDA)](2)[(E')C(PPh(2)E)(2)] (2b, E = E' = S; 2c, E = S, E' = Se, respectively). All new compounds have been characterized in solution by (1)H and (31)P NMR spectroscopy and the solid-state structures have been determined for 8, 9c and 10a-c by single-crystal X-ray crystallography. Complex 8 is comprised of Tl(+) ions that are weakly coordinated to octahedral [Tl{(Se)C(PPh(2)Se)(2)}(2)](-) anions to give a one-dimensional polymer. The complex 9c is comprised of two four-coordinate Tl(+) ions that are each S,S',S'',Se bonded to the hexadentate [(SPh(2)P)(2)CSeSeC(PPh(2)S)(2)](2-) ligand in which d(Se-Se) = 2.531(2) Å. The six-coordinate In(III) centres in the distorted octahedral complexes 10a-c are connected to a tridentate [(E')C(PPh(2)E)(2)](2-) dianion, a chloride ion and a neutral bidentate TMEDA ligand." @default.
• W1985446938 created "2016-06-24" @default.
• W1985446938 creator A5043132299 @default.
• W1985446938 creator A5052240063 @default.
• W1985446938 creator A5085077320 @default.
• W1985446938 date "2011-01-01" @default.
• W1985446938 modified "2023-10-10" @default.
• W1985446938 title "Homoleptic, heteroleptic and mixed-valent thallium and indium complexes of multidentate chalcogen-centred PCP-bridged ligands" @default.
• W1985446938 cites W1967237480 @default.
• W1985446938 cites W1976689499 @default.
• W1985446938 cites W1978621590 @default.
• W1985446938 cites W1988198292 @default.
• W1985446938 cites W2004108994 @default.
• W1985446938 cites W2005115405 @default.
• W1985446938 cites W2009779706 @default.
• W1985446938 cites W2011647853 @default.
• W1985446938 cites W2011839345 @default.
• W1985446938 cites W2014071988 @default.
• W1985446938 cites W2020533262 @default.
• W1985446938 cites W2022416502 @default.
• W1985446938 cites W2030841140 @default.
• W1985446938 cites W2031167392 @default.
• W1985446938 cites W2041453078 @default.
• W1985446938 cites W2052303822 @default.
• W1985446938 cites W2052643805 @default.
• W1985446938 cites W2061276665 @default.
• W1985446938 cites W2066138376 @default.
• W1985446938 cites W2072435998 @default.
• W1985446938 cites W2083431833 @default.
• W1985446938 cites W2083813500 @default.
• W1985446938 cites W2108672596 @default.
• W1985446938 cites W2111939673 @default.
• W1985446938 cites W2121237359 @default.
• W1985446938 cites W2126141837 @default.
• W1985446938 cites W2150002066 @default.
• W1985446938 cites W2163842250 @default.
• W1985446938 cites W2329978757 @default.
• W1985446938 cites W2949875431 @default.
• W1985446938 cites W2950577909 @default.
• W1985446938 cites W4233744221 @default.
• W1985446938 cites W1980802566 @default.
• W1985446938 doi "https://doi.org/10.1039/c1dt10646e" @default.
• W1985446938 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21717021" @default.
• W1985446938 hasPublicationYear "2011" @default.
• W1985446938 type Work @default.
• W1985446938 sameAs 1985446938 @default.
• W1985446938 citedByCount "14" @default.
• W1985446938 countsByYear W19854469382012 @default.
• W1985446938 countsByYear W19854469382013 @default.
• W1985446938 countsByYear W19854469382015 @default.
• W1985446938 countsByYear W19854469382016 @default.
• W1985446938 countsByYear W19854469382018 @default.
• W1985446938 countsByYear W19854469382019 @default.
• W1985446938 countsByYear W19854469382022 @default.
• W1985446938 countsByYear W19854469382023 @default.
• W1985446938 crossrefType "journal-article" @default.
• W1985446938 hasAuthorship W1985446938A5043132299 @default.
• W1985446938 hasAuthorship W1985446938A5052240063 @default.
• W1985446938 hasAuthorship W1985446938A5085077320 @default.
• W1985446938 hasConcept C108204754 @default.
• W1985446938 hasConcept C115624301 @default.
• W1985446938 hasConcept C155647269 @default.
• W1985446938 hasConcept C158733187 @default.
• W1985446938 hasConcept C161790260 @default.
• W1985446938 hasConcept C178516000 @default.
• W1985446938 hasConcept C178790620 @default.
• W1985446938 hasConcept C179104552 @default.
• W1985446938 hasConcept C185592680 @default.
• W1985446938 hasConcept C2781083472 @default.
• W1985446938 hasConcept C2994067411 @default.
• W1985446938 hasConcept C544153396 @default.
• W1985446938 hasConcept C553756173 @default.
• W1985446938 hasConcept C559099789 @default.
• W1985446938 hasConcept C66974803 @default.
• W1985446938 hasConcept C71240020 @default.
• W1985446938 hasConcept C8010536 @default.
• W1985446938 hasConceptScore W1985446938C108204754 @default.
• W1985446938 hasConceptScore W1985446938C115624301 @default.
• W1985446938 hasConceptScore W1985446938C155647269 @default.
• W1985446938 hasConceptScore W1985446938C158733187 @default.
• W1985446938 hasConceptScore W1985446938C161790260 @default.
• W1985446938 hasConceptScore W1985446938C178516000 @default.
• W1985446938 hasConceptScore W1985446938C178790620 @default.
• W1985446938 hasConceptScore W1985446938C179104552 @default.
• W1985446938 hasConceptScore W1985446938C185592680 @default.
• W1985446938 hasConceptScore W1985446938C2781083472 @default.
• W1985446938 hasConceptScore W1985446938C2994067411 @default.
• W1985446938 hasConceptScore W1985446938C544153396 @default.
• W1985446938 hasConceptScore W1985446938C553756173 @default.
• W1985446938 hasConceptScore W1985446938C559099789 @default.
• W1985446938 hasConceptScore W1985446938C66974803 @default.
• W1985446938 hasConceptScore W1985446938C71240020 @default.
• W1985446938 hasConceptScore W1985446938C8010536 @default.
• W1985446938 hasIssue "32" @default.
• W1985446938 hasLocation W19854469381 @default.
• W1985446938 hasLocation W19854469382 @default.
• W1985446938 hasOpenAccess W1985446938 @default.
• W1985446938 hasPrimaryLocation W19854469381 @default.

• next