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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985449905> ?p ?o ?g. }

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• W1985449905 abstract "18,20-Epoxy-11β,17α,20β,21-tetrahydroxypregn-4-en-3-one was synthesized by the application of hypoiodite reaction to the cortisol acetonide. The intermediary 18-iodo derivative was converted to the 11-oxo steroid by chromic acid prior to silver ion-assisted solvolysis. Removal of the protective group with hydrochloric acid was finally carried out to give the desired 11β,17α,18,21-tetrahydroxypregn-4-ene3,20-dione as the hemiacetal form. 18,20-Epoxy-11β-17α,20β,21-tetrahydroxypregna-1,4-dien-3-one was also prepared from prednisolone through a similar reaction sequence." @default.
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• W1985449905 date "1992-09-01" @default.
• W1985449905 modified "2023-09-23" @default.
• W1985449905 title "Convenient synthesis of 18-hydroxylated cortisol and prednisolone" @default.
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• W1985449905 doi "https://doi.org/10.1016/0039-128x(92)90095-q" @default.
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