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- W1985452014 abstract "Gasförmiges Chlorazid reagiert bei O°C in guter Ausbeute mit SnCl4, TiCl4 und VOCl3 unter Bildung der kristallinen, hygroskopischen, explosiven Azidchloride SnCl3N3, TiCl3N3 und VOCl2N3. Nach den IR-Spektren liegen Inselstrukturen vor mit weitgehend homöopolaren MN3-Bindungen. (M = Sn, Ti Symmetrie C3v; M = V Symmetrie Cs.) Unter Lösungsmitteleinfluβ spalten TiCl3N3 und VOCl2N3 Stickstoff und Chlor ab, wobei sich die reinen, polymeren Nitridverbindungen TiNCl bzw. VON bilden. By reaction of gaseous chlorine azide with SnCl4, TiCl4 and VOCl3 at 0°C the crystalline, hygroscopic, explosive Azidechlorides SnCl3N3, TiCl3N3 and VOCl3N3 respectively can be obtained in good yields. Infra-red spectra show these compounds to be island-structures with great degree of nonpolar MN3-bondings (M = Sn, Ti symmetry C3v; M = V symmetry Cs). By interaction of solvents TiCl3N3 and VOCl2N3 split off N2 and Cl2 and the well-defined nitride-compounds TiNCl and VON are obtainable." @default.
- W1985452014 created "2016-06-24" @default.
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- W1985452014 date "1965-04-01" @default.
- W1985452014 modified "2023-09-26" @default.
- W1985452014 title "Darstellung und eigenschaften der azidchloride SnCl3N3, TiCl3N3 und VOCl2N3" @default.
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- W1985452014 doi "https://doi.org/10.1016/0022-1902(65)80441-9" @default.
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