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- W1985455854 abstract "The Crystal and molecular structures of the cis- and trans-isomers of dicarbonyltetra(dimethoxyphenylphosphine)manganese(I) hexafluorophosphate, [Mn(CO)2 {P(OMe)2Ph}4] [PF6], have been determined using X-ray diffraction data recorded on an automatic diffractometer. The cis-isomer is monoclinic, space group P2/c, a 14.51(1), b 9.42(1), c 18.60(2) Å, β 124.5(2)°, Z = 2. The trans-isomer is monoclinic, space group P21/n, a 22.99(3), b 14.38(2), c 14.21(2) Å, β 107.0(2)°, Z = 4. Both structures were refined anisotropically by full-matrix least-squares methods to give R-values of 0.067 and 0.076 respectively for the cis- and trans-isomers. Both structures contain discrete [Mn(CO)2 {P(OMe)2Ph}4]+ cations and [PF6]- anions." @default.
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- W1985455854 date "1976-05-01" @default.
- W1985455854 modified "2023-09-26" @default.
- W1985455854 title "The crystal and molecular structures of two isomers of dicarbonyltetra(dimethoxyphenylphosphine)-manganese(I) hexafluorophosphate" @default.
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- W1985455854 doi "https://doi.org/10.1016/s0022-328x(00)87134-x" @default.
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