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- W1985462010 abstract "The steady state and time-resolved fluorescence study of 2-amino-5,6-dimethyl-benzimidazole (ADBI) have been studied in aqueous solution of β-cyclodextrin (β-CD). The fluorescence decays were analyzed by global analysis and distribution analysis in order to get insight about the inclusion process. The fluorescence lifetime of ADBI is increased in β-CD and an enhancement of the emission, is observed, together with negligible changes in the energy of ADBI in β-CD. The experimental data show that β-CD reacts with ADBI to form a 1:1 host–guest complex with association constant was determined to be 2074±77 M−1. Both global analysis and distribution analysis of the fluorescence decays support the formation of only 1:1 inclusion complex. AM1 calculation shows that the size of ADBI was appropriate for good insertion within the β-CD cavity and the inclusion of ADBI inside the β-CD cavity should takes place from the side of the amino group substituent." @default.
- W1985462010 created "2016-06-24" @default.
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- W1985462010 date "2004-02-06" @default.
- W1985462010 modified "2023-09-26" @default.
- W1985462010 title "Global and distribution analysis of fluorescence decays and spectrofluorimetric determination of stoichiometry and association constant of the inclusion complex of 2-amino-5,6-dimethyl-benzimidazole with β-cyclodextrin" @default.
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- W1985462010 doi "https://doi.org/10.1016/j.talanta.2003.07.009" @default.
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