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• W1985474014 startingPage "2125" @default.
• W1985474014 abstract "Infrared fluorescence has been observed from a monolayer of $^{13}mathrm{C}^{16}$O on NaCl(100) following vibrational excitation of its fundamental absorption band with a pulsed CO gas laser. Direct time-domain measurements of the fluorescence reveal a lifetime of 4.3 ms. Since fluorescence occurs in the overtone region from high vibrational states, these results demonstrate that energy can be stored in the adsorbate long enough to allow vibrational up-pumping between neighboring molecules. It is suggested that the primary channel for CO vibrational relaxation is ensuremath{Delta}v=-1 transfer to phonons of the NaCl substrate." @default.
• W1985474014 created "2016-06-24" @default.
• W1985474014 creator A5035084130 @default.
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• W1985474014 date "1990-10-22" @default.
• W1985474014 modified "2023-09-29" @default.
• W1985474014 title "Infrared fluorescence from a monolayer of CO on NaCl(100)" @default.
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• W1985474014 doi "https://doi.org/10.1103/physrevlett.65.2125" @default.
• W1985474014 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10042460" @default.
• W1985474014 hasPublicationYear "1990" @default.
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