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- W1985474977 abstract "We report on in situ, interference-enhanced Raman-scattering studies of ultrathin, several monolayer thick films that demonstrate solid-solution formation of ${mathit{A}}_{mathit{x}}$${mathrm{C}}_{60}$ for A=NA, K, Rb, Cs and xensuremath{le}3. In contrast to ${mathrm{Na}}_{mathit{x}}$${mathrm{C}}_{60}$, which indicates moderate, disorder-related vibrational broadening, the other alkali-metal--fulleride Raman spectra exhibit larger changes in intramolecular ${mathrm{C}}_{60}$ derived Hg(2) and Hg(8) modes due to substantial electron-phonon coupling. These observations are consistent with the absence of superconductivity in ${mathrm{Na}}_{mathit{x}}$${mathrm{C}}_{60}$ and comparable, substantial electron-phonon coupling in ${mathrm{K}}_{mathit{x}}$${mathrm{C}}_{60}$ and ${mathrm{Rb}}_{mathit{x}}$${mathrm{C}}_{60}$. For ${mathrm{Cs}}_{mathit{x}}$${mathrm{C}}_{60}$, the largest electron-phonon coupling for Hg(2) is observed for xensuremath{simeq}1, in contrast to values of xensuremath{simeq}2 for K and Rb doped materials." @default.
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- W1985474977 date "1992-08-01" @default.
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- W1985474977 title "Variations of electron-phonon coupling in alkali-metal–C60solid solutions" @default.
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- W1985474977 doi "https://doi.org/10.1103/physrevb.46.3696" @default.
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